[45] On the energetics of binding and hydrides exchange in the RuH2(H2)2[P(C5H9)3)]2 Complex as Revealed by Inelastic Neutron Scattering and DFT Studies.
A. Albinati, M. Grellier, J. Ollivier, P. A. Georgiev
A. Mejia Fajardo, N. Queyriaux, A. Camy, L. Vendier, M. Grellier, I. del Rosal, L. Maron, S. Bontemps
Chem. Eur. J. 2022, 28, e202104122. abstract
[43] Impact of the
Alkali Metal on the Structural and Dynamic Properties of the Anionic Pentahydride Ruthenium Complexes [M(THF)x][RuH5(PCy3)2] (M = Li, Na,
K)
R. Ayyappan, K. Saha, M. Grellier, E. Clot, L. Vendier, S. Ghosh, S. Sabo-Etienne, and S. Bontemps
Organometallics. 2021, 40, 3024-3032 Abstract.
[42] Hydrogen-Bond-Guided Reaction of Cyclohexadienone-aldehydes with Amines: Synthesis of an Aminal Group Containing a Fused Tetracyclic
Framework
Anil Chauhan, Raj Kumar Patel, Mary Grellier and Ravindra Kumar
Org. Lett. 2020, 15, 6177–6181 Abstract
[41] Improved
hydrogen storage properties of Mg/MgH2 thanks to the addition of nickel hydride complex precursors
B. Galey, A. Auroux, S. Sabo-Etienne, S. Dhaher, M. Grellier, G. Postole
Int. J. Hydrog. Energy, 2019, 44, 28848-28862 Abstract
[40] Enhancing hydrogen storage properties of the Mg/MgH2 system by the addition of bis(tricyclohexylphosphine)nickel(II)
dichloride
[38] Impact of the addition of poly-dihydrogen ruthenium precursor complexes on the hydrogen storage properties of the Mg/MgH2
system
B. Galey, A. Auroux, S. Sabo-Etienne, M. Grellier, Sameh Dhaher, G. Postole
Sustainable Energy Fuels, 2018, 2, 2335-2344 Abstract
[37] Ortho-phenyl dialkylphosphonium sulfonate compounds: two rotamers in equilibrium
E. Martin-Mothes, E. Puig, L. Vendier, C. Bijani, M. Grellier, S. Bontemps
Dalton Transactions, 2018, 47, 10139-10146 Abstract
[36] Modulation of an Anagostic Interaction in SiPSi-Type Pincer Platinum Complexes
J. Zamora-Moreno, F. Murillo, M. A. Muñoz-Hernández, M. Grellier, S. Pan, S. Jalife, G. Merino, S. Sabo-Etienne, V. Montiel-Palma
Organometallics, 2018, 37, 3581–358 Abstract
[35] Transition-Metal-Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate
K. Kikushima, M. Grellier, M. Ohashi, S. Ogoshi
Angew. Chem. Int. Ed. 2017, 56, 16191-16196 Abstract
[34] N-Heterocyclic Carbene Iron Silyl Hydride Complexes
S. Quintero-Duque, H. Li, L. C. Misal Castro, V. Dorcet, T. Roisnel, E. Clot, M. Grellier, J.-B. Sortais, C. Darcel
Isr. J. Chem., 2017, 57, 1216–1221 Abstract
[A] Acknowledgement for discussion on mechanistic part in:
R. Kumar, Y. Hoshimoto, E. Tamai, M. Ohashi, and S. Ogoshi
Nat. Commun. 2017, 8, 32. Abstract
[33] A family of rhodium and iridium complexes with semirigid benzylsilyl phosphines: from bidentate to tetradentate coordination modes
M. V. Corona-González, J. Zamora-Moreno, C. A. Cuevas-Chávez, E. Rufino-Felipe, E. Mothes-Martin, Y. Coppel, M. A. Muñoz-Hernández, L. Vendier, M. Flores-Alamo, M.
Grellier, S. Sabo-Etienne and V. Montiel-Palma
Dalton Transactions, 2017, 46, Abstract
[32] Direct Synthesis of Dicarbonyl PCP-Iron Hybride Complexes and Catalytic Dehydrogenative Borylation of Styrene
S. Jiang, S. Quintero-Duque, T. Roisnel, V. Dorcet, M. Grellier, S. Sabo-Etienne, C. Darcel and J.-B. Sortais
Dalton Transactions, 2016, 45, 11101-11108 Abstract
[31] A Ruthenium Dihydrogen Germylene Complex and the Catalytic Synthesis of Digermoxane
K. A. Smart, E. Mothes-Martin, L. Vendier, R. N. Perutz, M. Grellier, and S. Sabo-Etienne
Organometallics, 2015, 34, 4158–4163 Abstract
[30] Iron-Catalyzed C–H Borylation of Arenes
T. Dombray, C. G. Werncke, S. Jiang, M. Grellier, L. Vendier, S. Bontemps, J.-B. Sortais, S. Sabo-Etienne, and C. Darcel
J. Am. Chem. Soc., 2015, 137, 4062–4065 Abstract
[29] New perspectives in hydrogen storage based on RCH2NH2/RCN couples
M. Grellier and S. Sabo-Etienne
Dalton Trans., 2014, 43, 6283-6286. Abstract
2014’s most accessed Dalton Transactions articles
[28] Silane Deuteration Catalyzed by Ruthenium Bis(dihydrogen) Complexes or Simple Metal Salts
K. A. Smart, E. Mothes-Martin, T. Annaka, M. Grellier and S. Sabo-Etienne
Adv. Synth. Catal. 2014, 356 , 759–764 Abstract
[27] Nature of Si–H Interactions in a Series of Ruthenium Silazane Complexes Using Multinuclear Solid-State NMR and Neutron Diffraction
K. A. Smart, M. Grellier, Y. Coppel , L. Vendier, S. A. Mason, S. C. Capelli, A. Albinati , V. Montiel-Palma, M. A. Muñoz-Hernández, and S. Sabo-Etienne
Inorg. Chem. 2014, 53, 1156–1165 Abstract
[26] Phosphinodi(benzylsilane) PhP[(o-C6H4CH2)SiMe2H]2 : A Versatile “PSi2Hx” Pincer-Type Ligand at Ruthenium
V. Montiel-Palma, M. A. Muñoz-Hernández, C. A. Cuevas-Chávez, L. Vendier, M. Grellier, and S. Sabo-Etienne
Inorg. Chem. 2013, 52, 9798–9806 Abstract
[25] Probing Highly Selective H/D Exchange Processes with a Ruthenium Complex through Neutron Diffraction and Multinuclear NMR Studies.
M. Grellier, S. A. Mason, A. Albinati, S. C. Capelli, S. Rizzato, C.Bijani, Y. Coppel, and S. Sabo-Etienne
Inorg. Chem. 2013, 52, 7329–7337 Abstract
[24] Step-by-Step Introduction of Silazane Moieties at Ruthenium : Different Extents of Ru–H–Si Bond Activation
Katharine A. Smart, Mary Grellier, Laure Vendier, Sax A. Mason, Silvia C. Capelli, Alberto Albinati and Sylviane Sabo-Etienne
Inorg. Chem. 2013, 52 , 2654–2661. Abstract
[23] Feature Article :
Dehydrogenation processes via C–H activation within alkylphosphines
M. Grellier, S. Sabo-Etienne
Chem. Commun., 2012, 48, 34-42. Abstract
[22] Ruthenium-Catalyzed Hydrogenation of Nitriles : Insights into the Mechanism
R. Reguillo, M. Grellier, N. Vautravers, L. Vendier, S. Sabo-Etienne
J. Am. Chem. Soc., 2010, 132 , 7854–7855 Abstract
[21] Motional heterogeneity in single-site silica-supported species revealed by deuteron NMR
J. Gath, G. L. Hoaston, R. L. Vold, R. Berthoud, C. Copéret, M. Grellier, S. Sabo-Etienne, A. Lesage, L. Emsley
Phys. Chem. Chem. Phys., 2009, 11, 6962 - 6971 Abstract
[20]Bis σ-Bond Dihydrogen and Borane Ruthenium Complexes : Bonding Nature, Catalytic Applications, and Reversible Hydrogen Release
G. Alcaraz, M. Grellier, S. Sabo-Etienne
Acc. Chem. Res.2009, 42 ,1640–1649 Abstract
[19] Versatile Coordination of 2-Pyridinetetramethyldisilazane at Ruthenium : Ru(II) vs Ru(IV) As Evidenced by NMR, X-ray, Neutron, and DFT Studies
M. Grellier, T. Ayed, J.-C. Barthelat, A. Albinati, S. Mason, L. Vendier, Y. Coppel, and S. Sabo-Etienne
J. Am. Chem. Soc. 2009, 131, 7633. Abstract
[18] Access to Ruthenium(0) Carbonyl Complexes via Dehydrogenation of a Tricyclopentylphosphine Ligand and Decarbonylation of Alcohols
P. D. Bolton, M. Grellier, N. Vautravers, L. Vendier, S. Sabo-Etienne*
Organometallics, 2008, 27, 5088–5093.Abstract
[17] Synthesis and Reactivity of Ruthenium Arene Complexes Incorporating Novel Ph2PCH2CH2BR2 Ligands. Easy Access to the Four-Membered Ruthenacycle [(p-cymene)RuCl(κC,P-CH2CH2PPh2)]
J. Vergnaud, M. Grellier, G. Bouhadir, L. Vendier, S. Sabo-Etienne, D. Bourissou
Organometallics , 2008, 27, 1140. Abstract
[16] Agostic Si–H bond coordination assists C–H bond activation at ruthenium in bis(phosphinobenzylsilane) complexes.
V. Montiel-Palma, M. A. Munoz-Hernandez, T. Ayed, J.-C. Barthelat, M. Grellier, L. Vendier, S. Sabo-Etienne,
Chem. Comm. 2007, 3963.Abstract
[15] Synthesis, structure and coordination of the ambiphilic ligand (2-picolyl)BCy2
J. Vergnaud, T. Ayed, K. Hussein, L. Vendier, M. Grellier, G. Bouhadir, J.-C. Barthelat, S. Sabo-Etienne, D. Bourissou,
Dalton Transactions 2007, 2370.Abstract
[14] Ruthenium Complexes Carrying Hydride, Dihydrogen, and Phosphine Ligands : Reversible Hydrogen Release
M. Grellier, L. Vendier, S. Sabo-Etienne
Angew. Chem., Int. Ed. 2007, 46, 2613.Abstract
[13] Cobalt
M. Pfeffer,M. Grellier,
E. R. Crabtree, M. Mingos, Elsevier.,
Comprehensive Organometallic Chemistry III 2006.
[12] Synthesis, Neutron Structure, and Reactivity of the Bis(dihydrogen) Complex RuH2(eta2-H2)2(PCyp3)2 Stabilized by Two Tricyclopentylphosphines
M. Grellier, L. Vendier, B. Chaudret, A. Albinati, S. Rizzato, S. Mason, S. Sabo-Etienne,
J. Am. Chem. Soc. 2005, 127, 17592.Abstract
[11] Structure and Bonding in a Disilazane Ruthenium Complex. Catalytic Selective Deuteration of Disilazane
T. Ayed, J.-C. Barthelat, B. Tangour, C. Pradere, B. Donnadieu, M. Grellier, S. Sabo-Etienne
Organometallics 2005, 24, 3824.Abstract
[10] Ruthenium : Inorganic and Coordination Chemistry.
S. Sabo-Etienne, M. Grellier.
Encyclopedia of Inorganic Chemistry . Editeur : R.B. King, John Wiley & Sons,Ltd. 2005, 7, 4757.
[9] Redistribution at silicon by ruthenium complexes. Bonding mode of the bridging silanes in Ru2H4(µ-2:2:2:2-SiH4)(PCy3)4 and Ru2H2(µ-2:2-H2Si(OMe)2)3(PCy3)2
R. Ben Said, K. Hussein, J.-C. Barthelat, I. Atheaux, S. Sabo-Etienne, M. Grellier, B. Donnadieu, B. Chaudret,
Dalton Transactions 2003, 4139.Abstract
[8] Pseudotetrahedral Organocobalt(III) Compounds Containing Specific Coordination Sites for Brønsted Acids
M. R. Meneghetti, M. Grellier, M. Pfeffer, A. De Cian, J. Fischer,
Eur. J. I. C. 2000, 1539.Abstract
[7] Reactivity of Cyclocobaltated Benzylamine Derivatives toward Terminal Alkynes
M. R. Meneghetti, M. Grellier, M. Pfeffer, J. Fischer,
Organometallics 2000, 19, 1935.Abstract
[6] Synthesis of Configurationally Stable, Optically Active Organocobalt Compounds
M. R. Meneghetti, M. Grellier, M. Pfeffer, J. Dupont, J. Fischer,
Organometallics 1999, 18, 5560.Abstract
[5] Palladium-Induced Intramolecular Pyridine-Allyl Coupling Reactions : Formation of N-Bridgehead Heterocycles with a Stable C-N Bond
J. Chengebroyen, M. Grellier, M. Pfeffer,
Eur. J.I.C. 1998, 1563.Abstract
[4] Allyl versus aryl C-H activation mediated by palladium acetate
M. Grellier, M. Pfeffer,
J. Organomet. Chem. 1997, 548, 301.Abstract
[3] Heterocyclization, deprotection and isomerization in an intramolecular palladium-catalysed tertiary amine–allyl coupling reaction
M. Grellier, M. Pfeffer,
Chem. Comm. 1996, 2257.Abstract
[2] Pd catalysed intramolecular coupling between tertiary amines and allylic groups ; synthesis of 3-hydro-1H-2-benzazepinium salts
M. Grellier, M. Pfeffer, G. van Koten,
Tetrahedron Letters 1994, 35, 2877.Abstract
[1] Palladium-Mediated Intramolecular C-N Bond Formation between Tertiary Amines and Alkenes
P. A. van der Schaaf, J.-P. Sutter, M. Grellier, G. P. M. van Mier, A. L. Spek, G. van Koten, M. Pfeffer,
J. Am. Chem. Soc. 1994, 116, 5134.Abstract
Dr Mary GRELLIER
Maitre de
Conférences
Laboratoire de Chimie de Coordination, CNRS
UPR 8241
BP 44099
205, route de Narbonne
31077 TOULOUSE Cédex 4
FRANCE
e-mail: mary.grellier@lcc-toulouse.fr
Tel : +33 (0)5 61 33 31 77
Fax : +33 (0)5 61 55 30 03
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